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By Duane W., Fricke H.

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It is the aim of the present chapter to review environmental studies involving heterogeneous photochemical processes and to introduce some relevant basic concepts needed for their understanding. Selected examples are presented and discussed in some detail. Whenever possible, emphasis is given to the interrelation between field and laboratory studies. General concepts are introduced in Sect. 2 and specific examples are given in Sect. 3. These examples refer to heterogeneous reactions occurring in the atmosphere, waters and soil.

It is the aim of the present chapter to review environmental studies involving heterogeneous photochemical processes and to introduce some relevant basic concepts needed for their understanding. Selected examples are presented and discussed in some detail. Whenever possible, emphasis is given to the interrelation between field and laboratory studies. General concepts are introduced in Sect. 2 and specific examples are given in Sect. 3. These examples refer to heterogeneous reactions occurring in the atmosphere, waters and soil.

57 57 57 58 62 63 65 67 69 4 Conclusions . . . . . . . . . . . . . . . . . . 72 References . . . . . . . . . . . . . . . . . . . . 73 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Abstract Heterogeneous reactions are widespread in all the environmental compartments: soils, hydrosphere, troposphere and at medium altitudes in the stratosphere. In particular, heterogeneous photochemical processes are concerned with the effect of light on interacting molecules and solid surfaces.

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