By Herbert Schumann, Ingeborg Schumann, Ulrich Krüerke, Rainer Bohrer, Bernd Kalbskopf, Hans-Jürgen Richter-Ditten
The importance of organometallic chemistry has consistently elevated in the course of the moment half this century. inside this quarter of study the organotin chemistry reigns as some of the most vital branches. The decisive reason behind this improvement has been the wide variety of power software of those compounds in undefined, expertise, and agriculture. the current quantity maintains the sequence on Organotin Compounds, which first seemed in 1975 and now includes a set of 16 volumes. the general plan of the sequence has been given within the preface of quantity 1. This quantity concludes the outline of the mononuclear organotin compounds with tin-oxygen bonds. therapy of organotin compounds with tin-sulfur, -selenium, and -tellurium bonds seemed previous within the Volumes nine and 10. quantity 17 describes intimately the next compound kinds: RSn(OR')3, RSn(OR')2OR," R2Sn(X)OR', RSnX(OR')2, and RSnX2(OR').
Read or Download Sn Organotin Compounds: Part 17: Organotin-Oxygen Compounds of the Types RSn(OR′)3 and RSn(OR′)2OR″; R2Sn(X)OR′, RSnX(OR′)2, and RSnX2(OR′) PDF
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Additional info for Sn Organotin Compounds: Part 17: Organotin-Oxygen Compounds of the Types RSn(OR′)3 and RSn(OR′)2OR″; R2Sn(X)OR′, RSnX(OR′)2, and RSnX2(OR′)
31  207/9).  Kennedy, J. D. (J. Chem. soc. Perkin Trans. 11 1977 242/8). ; Coucouvanis, D. (Inorg. Chem. 16  1611/4).  Petridis, D. (Inorg. Chem. 17  3719/21).  Knoth, W. H. (J. Am. Chem. soc. 101  759/60). ; Engelhardt. ; Mägi. ; Larin. M. ; Pestunovich. V. A; Voronkov, M. G. (J. Organometal. Chem. 171  301/8).  Zonnevijlle. ; Pope, M. T. (J. Am. Chem. soc. 101  2731/2). ; Fischer, G. W. (Z. Anorg. Allgem. Chem. 463 123/31). , Ud. (Japan.
However, although the two terminal tin atoms are crystallographically equivalent owing to the disorder, they are not chemically equivalent. This is consistent with three types of tin atoms and three types of methyl protons indicated by the NMR spectra. Assuming that the solid state structure is the one present also in solution, the fluxional behavior implied by the NMR data can be explained bya ligand-exchange mechanism . Gmelin Hendbook Organotin 17 References on p. 23 2' 20 Table 2 NMR Data of CH3Sn(OCH2CH2)3N .
19711073). ; Koola, J. (J. Organometal. Chem. 31  59/66). ; Burger, K. (J. Organometal. Chem. 59  199/206). ; Pönicke, K. (J. Organometal. Chem. 51  197/201). Kennedy, J. ; McFarlane, W. (Rev. Silicon Germanium Tin Lead Chem. 1  235/98). ; sharma, H. ; Carty, A. ; Walker, A (Inorg. Chem. 13  1205/11). van den Berghe, E. ; van der Kelen, G. P. (J. Mol. struct. 20  147/52). ; Miller, J. M. (J. Chem. soc. Dalton Trans. 1975393/5). Tzschach, A; Pönicke, K. (Z. Anorg.
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