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By Bernhard Kräutler, N. P. Sahu

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Mode of Formation of Red Pigments. Plant Cell Physiol 10: 51 Chlorophyll Catabolites 43 106. Iturraspe J, Engel N, Gossauer A (1994) Chlorophyll Catabolism. 5. Isolation and Structure Elucidation of Chlorophyll b Catabolites in Chlorella protothecoides. Phytochem 35: 1387 107. Curty C, Engel N (1997) Chlorophyll Catabolism: High Stereoselectivity in the Last Step of the Primary Ring Cleaving Process. Plant Physiol Biochem 35: 707 108. Raven HP, Evert RF, Eichhorn SE (1987) Biology of Plants. Worth Publishers, New York 109.

1. Mass Spectrometry . . . . . . . . . . . . . . . . 2. NMR Spectroscopy . . . . . . . . . . . . . . . . 1. 1H NMR Spectroscopy . . . . . . . . . . . . 2. 13C NMR Spectroscopy. . . . . . . . . . . . 3. 2D NMR Spectroscopy . . . . . . . . . . . . . . . . . . . . . 49 50 52 55 55 57 57 58 59 4. Biological Activity . . . . . . . . . . . . . . . . . . . . 1. Cytotoxic Activity Against Cancer Cell Lines.

Characterization of Chlorophyll Catabolites and of Chlorophyll Catabolic Enzymes Involved in the Degreening Reaction. Plant Physiol 139: 52 61. Scheer H (1991) Structure and Occurrence of Chlorophylls. ) Chlorophylls, p. 3. CRC Press, Boca Raton, FL, USA 62. Mu¨hlecker W, Ongania KH, Kra¨utler B, Matile P, Ho¨rtensteiner S (1997) Tracking Down Chlorophyll Breakdown in Plants: Elucidation of the Constitution of a ‘‘Fluorescent’’ Chlorophyll Catabolite. Angew Chem Int Ed 36: 401 63. Matile P, Schellenberg M, Peisker C (1992) Production and Release of a Chlorophyll Catabolite in Isolated Senescent Chloroplasts.

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