Download Higher Oxidation State Organopalladium and Platinum by Kyle A. Grice, Margaret L. Scheuermann (auth.), Allan J. PDF

By Kyle A. Grice, Margaret L. Scheuermann (auth.), Allan J. Canty (eds.)

Kyle A. Grice, Margaret L. Scheuermann and Karen I. Goldberg: Five-Coordinate Platinum(IV) Complexes.- Jay A. Labinger and John E. Bercaw: The position of upper Oxidation country Species in Platinum-Mediated C-H Bond Activation and Functionalization.- pleasure M. Racowski and Melanie S. Sanford: Carbon-Heteroatom Bond-Forming Reductive removing from Palladium(IV) Complexes.- Helena C. Malinakova: Palladium(IV) Complexes as Intermediates in Catalytic and Stoichiometric Cascade Sequences supplying advanced Carbocycles and Heterocycles.- Allan J. Canty and Manab Sharma: h1-Alkynyl Chemistry for the better Oxidation States of Palladium and Platinum.- David C. Powers and Tobias Ritter: Palladium(III) in Synthesis and Catalysis.- Marc-Etienne Moret: Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d10 and s2 Centers.

Show description

Read or Download Higher Oxidation State Organopalladium and Platinum Chemistry PDF

Best chemistry books

Biogeochemical Cycles in Globalization and Sustainable Development (Springer Praxis Books Environmental Sciences)

This e-book opens new method of the learn of world environmental adjustments having unfourable personality for peoples and different residing structures. major good thing about this publication is composed within the accumulation of information from various sciences to parameterize international biogeochemical cycles within the context of globalization and sustainable improvement.

Non-Linear Dynamics and Fundamental Interactions (NATO Science Series II: Mathematics, Physics and Chemistry)

The booklet is directed to researchers and graduate scholars pursuing a sophisticated measure. It presents info of innovations directed in the direction of fixing difficulties in non-linear dynamics and chos which are, quite often, now not amenable to a perturbative remedy. the respect of primary interactions is a first-rate instance the place non-perturbative thoughts are wanted.

Extra resources for Higher Oxidation State Organopalladium and Platinum Chemistry

Sample text

Notably, intermolecular dehydrogenation of solvent was observed when intramolecular dehydrogenation was not possible. A. Grice et al. Scheme 8 C–C Reductive elimination from 1a and 3 and H–D exchange [92] olefin hydride complex [90]. The Pt(II) neohexene hydride was capable of performing stoichiometric transfer dehydrogenation in cyclohexane solvent to form the Pt(II) cyclohexene hydride and free neohexane. However, no catalytic transfer dehydrogenation of cyclohexane was observed with excess neohexene.

More recent calculations by that group, however, seem to prefer the oxidative addition route [55]. Both groups, as well as another [56], find that the barrier to coordination of methane is higher than that for C–H activation, as in most of the findings for the Shilov system itself (see above). An attempt to assess the probable effect of protonation of a free N in bipym by comparing the reactivity (for H/D exchange) of the N-methylated complex was thwarted by the facile demethylation observed under reaction conditions [57].

2 Stoichiometric C–H Activation at Ligated Pt(II) . . . . . . . . . . . . . . . . . . 3 Oxidation by Dioxygen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 5 Conclusions and Prospects . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Download PDF sample

Download Higher Oxidation State Organopalladium and Platinum by Kyle A. Grice, Margaret L. Scheuermann (auth.), Allan J. PDF
Rated 4.14 of 5 – based on 17 votes