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By Prof. J. Bermejo Barrera, Dr. H. J. M. Gijsen, Dr. A. G. González, Prof. Dr. Ae. de Groot, Prof. Dr. G. Prota, Dr. J. B. P. A. Wijnberg (auth.), Prof. W. Herz, Prof. G. W. Kirby, Prof. R. E. Moore, Prof. Dr. W. Steglich, Prof. Dr. Ch. Tamm (eds.)

Contents: A.G. González and J. Bermejo Barrera: Chemistry and resources of Mono- and Bicyclic Sesquiterpenes from Ferula Species. - G. Prota: The Chemistry of Melanins and Melanogenesis. - H.J.M. Gijsen, J.B.P.A. Wijnberg, and Ae. de Groot: constitution, prevalence, Biosynthesis, organic task, Synthesis, and Chemistry of Aromadendrane Sesquiterpenoids. The volumes of this vintage sequence, now spoke of easily as "Zechmeister” after its founder, L. Zechmeister, have seemed below the Springer Imprint ever because the sequence’ inauguration in 1938. The volumes include contributions on a variety of issues relating to the beginning, distribution, chemistry, synthesis, biochemistry, functionality or use of assorted periods of evidently taking place components starting from small molecules to biopolymers. each one contribution is written through a famous authority in his box and offers a complete and updated assessment of the subject in query. Addressed to biologists, technologists, and chemists alike, the sequence can be utilized by means of the professional as a resource of data and literature citations and by way of the non-expert as a method of orientation in a speedily constructing self-discipline.

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Tenuisecta F. soongarica F. akitschensis F. akitschensis F. elaeochytris F. pal/ida F. tenuisecta F. rigidula F. jaeschkeana F. elaeochytris F. tenuisecta F. orientalis F. soongarica F. pallida F. jaeschkeana F. rigidula F. elaeochytris F. jaeschkeana F. rigidula F. jaeschkeana F. jaeschkeana F. pallida F. sinaica F. rigidula (121) (126,127) (134) (54) (125) (134) (125) (125) (144) (122) (134) (104) (119) (128) (54) (121) (133) (134) (125) (54) (136) (23) (104) (121) (122) (123,124) (120) (79) (79) (119) VI VI '"'" O.

Jaeschkeana F. jaeschkeana F. jaeschkeana Vatke F. jaeschkeana Vatke F. jaeschkeana Vatke F. sinaica F. tingitana L. F. tingitana L. F. tingitana L. F. tingitana L. F. g '" ::;(62) (33,79) (146) (33,79) (33,79) (63) (63) (63) (63) (79) (62) (122) (63) (60) (60) (62) tn CD '" VI .... '" "'l ~ ::s CD ~. 0 (63) (118,149) (58) (125) (127) (53) (53) (57) (57) (122) (68,69) ~ '" I 'C '" 00 ~ '" "'" '~;:," ~ Unnamed Unnamed Akitschenin Unnamed Unnamed 5oc-(4-Hydroxybenzoyl)-9p-angeloxyjaeschkeanadiol Isofercomin Isolancerotriol-2-epi-5-p-hydroxybenzoate 3-5oc,IOP- Trihydroxy-2oc-p-hydroxybenzoyloxyp-hydroxybenzoyloxy-daucane Unnamed 5oc, 1Op- Dihydroxydauc-2-ene-l-one 5oc-p-Hydroxybenzoyloxy1O-hydroxy-dauc-2-ene-l-one 5oc,Sp- Diangeloyloxy-l Op- hydroxydauc-2-ene-l-ene Lapidol Lapidol isobutyrate Lapidol 2-methylbutyrate Lapidol p-anisate Lapidol p-hydroxybenzoate Lapidin Lapidol vanillate Palliferin Palliferinin Fercomin = (218) (179) (180) (181) (182) (183) (184) (185) (186) (187) (199) (200) (201) (202) (203) (204) (205) (206) (207) (208) (209) (188) (189) (190) Name of compound Structure number C 23 H 30 0 6 C2sH3407 C24H3007 C23H300S C22H3606 C 15 H 24 0 3 C19H3004 C 2o H 32 0 4 C23H300S C22H280S C2oH3004 C29H4007 C24H320S C 27 H 36 0 6 C24H320S C2sH3406 C 27 H 36 0 6 C 23 H 30 O S C22H300S C22H3206 C22H3206 C22H3206 ClsH2403 C22H280S Formula Table 2 (continued) F.

The distribution and structures ofbicyclic sesquiterpenes from Ferula species are shown in Table 2 and Chart 19, respectively. References. pp. p p- oPP 1 1 Lapiferol type r-h'j,o_ -~ i --\ 0 Felikiol type Chart 18. Biogenesis of daucane derivatives with cis and trans ring fusion :>:l '" I 'C '" 00 ~ ~" ";:, S, ".... Formula C 15 H 26 O C23H320S ClsH2602 C22H3004 C 23 H 32 0 4 C 2o H 32 0 3 C24H340S Name of compound lO-Epijunenol Xeroferin 1aeschkeanadiol Ferutinin (jaeschkeanadiol p-hydroxybenzoate) laeschkeanadiol p-methoxybenzoate (Ferutidin) laeschkeanadiol angelate laeschkeanadiol veratrate Structure number (59) (70) (73) (87) (88) (89) (90) (35) (42) (43,125) (54) (119) F erula galbaniflua F.

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