By Author Unknown, William L Hase
This moment quantity within the sequence covers such subject matters as lengthy lived ion complexes, crossed beam reviews on ion-moleculaar reactions, the double-well version for ion-molecule reactions and complicated formation, and direct collision dynamics in fuel section nucleophilic substitution reactions
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Shao, J. ; Lewis, D. K. J. Phys. Chem. 1988, 92, 5123. 78. Shao, J. ; Morrow, J. C ; Fraser-Monteiro, M. J. Chem. Phys. 1987, 87, 5242. 79. Case, K. M. Phys. Rev. 1950, 80, 797. 80. Kubach, C. J. Chem. Educai. 1983, 60, 212. 81. ; Howell, J. M. J. Chem. Educai. 1983, 60, 207. 82. ; Thompson, D. , unpublished. 83. Dugan, J. V; Rice, J. ; Mago, J. L. Chem. Phys. Lett. 1969, 323, 3. 84. Clary, D. C. Ann. Rev. Phys. Chem. 1990, 41, 61. 85. Clary, D. C. J. Chem. Soc. Faraday Trans. 2 1987, 83, 139. 86.
Energy diagram of three C4HÔ + isomers showing the position of the excited electronic states and the barriers for isomerization. Taken with permission from Bunn and Baer. It is interesting that in the butadiene reaction, as in the previously mentioned butène ion dissociation, the H loss channel is hardly detected in the unimolecular dissociation even though it is the most exothermic channel. This appears to be another example of the angular momentum constraint, which imposes a barrier to H loss.
Abstracts of 23 Ann. , Am. Soc. Mass Spectrom. 1975, Houston. 73. Klots, C. ; Baer, T. J. Chem. Phys. 1977, 66, 5100. 74. ; Gilman, J. ; Weiss, M. ; Meisels, G. G. J. Phys. Chem. 1981, 85, 2722. 75. ; Tsai, B. ; Werner, A. W Adv. Mass Spectrom. 1978, 7A, 56. 76. Brand, W. ; Baer, T. J. Am. Chem. Soc. 1984,106, 3154. 77. Shao, J. ; Lewis, D. K. J. Phys. Chem. 1988, 92, 5123. 78. Shao, J. ; Morrow, J. C ; Fraser-Monteiro, M. J. Chem. Phys. 1987, 87, 5242. 79. Case, K. M. Phys. Rev. 1950, 80, 797.
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