Download Conducting and Magnetic Organometallic Molecular Materials by John A. Schlueter (auth.), Marc Fourmigué, Lahcène Ouahab PDF

By John A. Schlueter (auth.), Marc Fourmigué, Lahcène Ouahab (eds.)

For numerous years, the 2 parallel worlds of Molecular Conductors in a single hand and Molecular Magnetism within the different have grown aspect by means of aspect, the previous primarily in response to radical natural molecules, the latter basically in line with the excessive spin homes of steel complexes. over the past few years besides the fact that, organometallic derivatives have began to play an more and more vital position in either worlds, and feature in lots of methods contributed to open a number of passages among those worlds. This quantity acknowledges this significant rising evolution of either examine parts. it isn't meant to provide a entire view of all attainable organometallic fabrics, and polymers for instance weren't thought of right here. fairly we current a variety of the latest learn themes the place organometallic derivatives have been proven to play a vital position within the environment of carrying out and/or magnetic homes in crystalline fabrics. First, the position of organometallic anions in tet- thiafulvalenium-based molecular conductors is highlighted by means of Schlueter, whereas Kubo and Kato describe very contemporary ortho-metalated chelating ligands appended to the TTF middle and their carrying out salts. the combo of accomplishing and magnetic houses and the quest for p–d interactions are analyzed in comp- mentary contributions by means of Myazaki and Ouahab, whereas Valade specializes in the one type of steel bis(dithiolene) complexes to provide upward thrust to superconductive molecular fabrics, in organization with natural in addition to organometallic cations.

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1 General Features of Molecular Conductors Since the discovery of the first organic semiconductor perylene-bromine complex in 1954 [1], a large number of molecular conductors, including more than 100 molecular superconductors, have been prepared. Conducting molecular materials are characterized by the following features; 1. Clear and simple electronic structure which can be well described by the tight-binding band picture based on the extended Hu¨ckel molecular orbital calculation [2] 2.

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