Download Advances in Inorganic Chemistry, Vol. 49 by A. G. Sykes PDF

By A. G. Sykes

Advances in Inorganic Chemistry provides well timed and informative summaries of the present development in quite a few topic components inside of inorganic chemistry, starting from bio-inorganic to reliable kingdom. This acclaimed serial positive factors stories written by means of specialists within the region and is an critical reference for complicated researchers. each one quantity of Advances in Inorganic Chemistry comprises an index, and every bankruptcy is absolutely referenced.

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Rev. 1998, 98, 2167–2289. 5. ; van Eldik, R. Coord. Chem. , in press. 6. Hubbard, C. ; van Eldik, R. Instrum. Sci. Technol. 1995, 22, 1. 7. ; van Eldik, R. ; Oxford Univ. Press: Oxford, 1997; Chapter 6. 8. ; Merbach, A. E. Comments Inorg. Chem. 1992, 12, 341. 9. Lincoln, S. ; Merbach, A. E. Adv. Inorg. Chem. 1995, 42, 1. 10. ; Merbach, A. ; Roulet, R. ; Wiley: Chichester, 1996, p. 193. 11. ; Petterson, L. G. ; Wahlgren, U. J. Am. Chem. Soc. 1994, 116, 8691. 12. ; Petterson, L. G. ; Wahlgren, U.

5 cm3 molϪ1. Measurements on a series of Cr, Co, and Ru complexes (140) enabled a systematic differentiation to be made between intrinsic and solvational volume contributions associated with the redox process. It has in general been the objective of many mechanistic studies dealing with inorganic electron-transfer reactions to distinguish between outer- and inner-sphere mechanisms. Along these lines highpressure kinetic methods and the construction of reaction volume profiles have also been employed to contribute toward a better understanding of the intimate mechanisms involved in such processes.

3 A His-70 and His-83, respectively. This decrease in the rate constant was accompanied by an increase in ⌬V # from ϩ4 to ϩ17 cm3 molϪ1. Within the context of the results reported above and the volume changes associated with the reduction of the Ru(III) ammine complexes, the gradual increase in ⌬V # with increasing donor–acceptor distance and with decreasing rate constant could be a clear demonstration of ‘‘early’’ (for the fast reactions) and ‘‘late’’ (for the slow reactions) transition states.

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